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王日權 發表於 2012-12-26 02:35 PM

麻煩一下 熱的問題

20.        When 0.7521 g of benzoic acid was burned in a calorimeter containing 1,000. g of water, a temperature rise of 3.60°C was observed.  What is the heat capacity of the bomb calorimeter, excluding the water?  The heat of combustion of benzoic acid is –26.42 kJ/g.
        A)        1.34 kJ/°C        D)        15.87 kJ/°C
        B)        4.18 kJ/°C        E)        752.1 kJ/°C
        C)        5.52 kJ/°C       


39.        Butane (C4H10) undergoes combustion in excess oxygen to generate gaseous carbon dioxide and water. Given H°f = –124.7 kJ/mol, H°f = –393.5 kJ/mol, H°f = –241.8 kJ/mol, how much energy is released (kJ) when 8.30 g of butane is burned?
                A)  22,100 kJ    B)  2,658.3 kJ    C)  379 kJ    D)  759 kJ    E)  2,910 kJ


75.        A gas is compressed in a cylinder from a volume of 20.0 L to 2.0 L by a constant pressure of 10.0 atm. Calculate the amount of work done on the system.
                A)  –1.81 × 104 J    B)  –180 J    C)  180 J    D)  1.01 × 104 J    E)  1.81 × 104 J


81.        At 25°C, the following heats of reaction are known:
2ClF(g) + O2(g)  Cl2O(g) + F2O(g)        H°rxn =  167.4 kJ/mol
2ClF3(g)+2O2(g)  Cl2O(g)+3F2O(g)        H°rxn =  341.4 kJ/mol
2F2(g) + O2(g)  2F2O(g)        H°rxn =  –43.4 kJ/mol       
At the same temperature, use the above data to calculate the heat released (kJ) when 3.40 moles of ClF(g) reacts with excess F2:
                          ClF(g) + F2(g)  ClF3(g)
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